NCERT Solutions for Class 10 Science Chapter 1 Activity 1.2

NCERT Solutions for Class 10 Science Chapter 1 Activity 1.2

Understanding Activity 1.2 🧐

Welcome to this comprehensive guide on NCERT Solutions for Class 10 Science Chapter 1 Activity 1.2. This practical activity demonstrates one of the most important types of chemical reactions – the double displacement reaction. In this experiment, we’ll observe how lead nitrate solution reacts with potassium iodide solution to form a beautiful yellow precipitate. This activity helps you understand how ions exchange partners during chemical reactions and provides visual evidence of chemical change. Let’s explore this fascinating reaction step-by-step with clear explanations and scientific reasoning!

🧪 Activity 1.2: Double Displacement Reaction

Activity Statement: Take lead nitrate solution in a test tube. Add potassium iodide solution to this. What do you observe?

Materials Required 📋

  • Lead nitrate solution (&&\ce{Pb(NO3)2}&&) – A colourless aqueous solution
  • Potassium iodide solution (&&\ce{KI}&&) – A colourless aqueous solution
  • Test tube – Clean and dry
  • Test tube holder – For safe handling
  • Dropper or pipette – For adding solutions
  • Safety equipment – Goggles and gloves (lead compounds are toxic)

⚠️ Safety Note: Lead nitrate is toxic. Handle with care under teacher supervision. Wear safety goggles and gloves throughout the experiment.

Detailed Procedure 🔬

Follow these steps carefully:

  1. Preparation: Take a clean, dry test tube and place it in a test tube holder for stability.
  2. Add Lead Nitrate: Pour approximately 2-3 mL of lead nitrate solution (&&\ce{Pb(NO3)2}&&) into the test tube. Notice that the solution is colourless and clear.
  3. Add Potassium Iodide: Using a dropper, carefully add 2-3 mL of potassium iodide solution (&&\ce{KI}&&) to the test tube containing lead nitrate solution. This solution is also colourless.
  4. Observe: Watch carefully as you add the potassium iodide solution. Note any changes in colour, formation of solid particles, or other visible changes.
  5. Wait: Allow the mixture to stand for a few minutes and observe if the solid settles at the bottom.

Observations 👁️

What You Will See:

Upon adding potassium iodide solution to the lead nitrate solution, you will observe the following changes:

  • 🟡 Immediate Formation of Yellow Precipitate: As soon as the two colourless solutions mix, a bright yellow precipitate forms instantly in the test tube.
  • ⬇️ Settling: After a few minutes, the yellow solid settles at the bottom of the test tube, while the liquid above remains clear.
  • 💧 Supernatant Liquid: The liquid remaining above the precipitate is a colourless solution of potassium nitrate (&&\ce{KNO3}&&).

The yellow precipitate formed is lead iodide (&&\ce{PbI2}&&), which is insoluble in water and therefore appears as a solid.


Detailed Explanation 🧪

Understanding the Chemical Reaction

When we mix lead nitrate solution with potassium iodide solution, a double displacement reaction (also called a double replacement reaction or metathesis reaction) occurs. In this type of reaction, the positive ions (cations) and negative ions (anions) of two different compounds exchange places to form two new compounds.

Think of it like a dance where partners swap! Initially, lead (&&\ce{Pb^{2+}}&&) is paired with nitrate (&&\ce{NO3^-}&&), and potassium (&&\ce{K^+}&&) is paired with iodide (&&\ce{I^-}&&). After the reaction, lead pairs up with iodide, and potassium pairs up with nitrate.

The Chemical Equation

The balanced chemical equation for this reaction is:

$$\ce{Pb(NO3)2(aq) + 2KI(aq) -> PbI2(s) + 2KNO3(aq)}$$

Breaking it down:

  • &&\ce{Pb(NO3)2}&&: Lead nitrate (aqueous, colourless)
  • &&\ce{KI}&&: Potassium iodide (aqueous, colourless)
  • &&\ce{PbI2}&&: Lead iodide (solid, yellow precipitate) ⭐
  • &&\ce{KNO3}&&: Potassium nitrate (aqueous, colourless)

The symbols in brackets indicate the physical state: (aq) means aqueous (dissolved in water), and (s) means solid (precipitate).

Why Does the Yellow Precipitate Form?

The formation of the yellow precipitate is the key observation in this activity. But why does it form? The answer lies in solubility.

Solubility Rules:

  • Lead nitrate (&&\ce{Pb(NO3)2}&&) is highly soluble in water, so it exists as separate &&\ce{Pb^{2+}}&& and &&\ce{NO3^-}&& ions in solution.
  • Potassium iodide (&&\ce{KI}&&) is also highly soluble in water, existing as &&\ce{K^+}&& and &&\ce{I^-}&& ions.
  • However, lead iodide (&&\ce{PbI2}&&) is insoluble in water at room temperature!
  • Potassium nitrate (&&\ce{KNO3}&&) is soluble in water and remains in solution.

When &&\ce{Pb^{2+}}&& ions from lead nitrate meet &&\ce{I^-}&& ions from potassium iodide in the solution, they immediately combine to form &&\ce{PbI2}&&. Since lead iodide cannot dissolve in water, it precipitates out as a bright yellow solid.

This is similar to when you mix oil and water – they don’t mix because oil is insoluble in water. Similarly, &&\ce{PbI2}&& cannot stay dissolved and must separate as a solid.

Type of Reaction

This activity demonstrates a double displacement reaction, which is also a type of precipitation reaction because a precipitate (insoluble solid) is formed.

General form of double displacement reaction:

$$\ce{AB + CD -> AD + CB}$$

Where A and C are cations (positive ions), and B and D are anions (negative ions). In our case:

  • A = &&\ce{Pb^{2+}}&&
  • B = &&\ce{NO3^-}&&
  • C = &&\ce{K^+}&&
  • D = &&\ce{I^-}&&

The cations and anions swap partners to form &&\ce{PbI2}&& and &&\ce{KNO3}&&.

Balancing the Equation

Notice the coefficient 2 before &&\ce{KI}&& and &&\ce{KNO3}&&. This is necessary to balance the equation:

Step-by-step balancing:

  1. Lead nitrate has 1 lead atom: &&\ce{Pb(NO3)2}&&
  2. It also has 2 nitrate groups (&&\ce{NO3^-}&&)
  3. Each lead ion (&&\ce{Pb^{2+}}&&) needs 2 iodide ions (&&\ce{I^-}&&) to form &&\ce{PbI2}&&
  4. Therefore, we need 2 molecules of &&\ce{KI}&& to provide 2 iodide ions
  5. This produces 2 molecules of &&\ce{KNO3}&& (2 potassium ions + 2 nitrate groups)

The balanced equation ensures that the number of atoms of each element is the same on both sides of the equation, following the Law of Conservation of Mass.

Connecting to Other Concepts

This activity is closely related to other important chemistry concepts you’ll learn in Chapter 1. For example, understanding types of chemical reactions helps you classify different reaction patterns. You can also explore more about precipitation reactions and solubility rules to predict when precipitates will form in other reactions.


Conclusion and Key Principles ✅

Activity 1.2 beautifully demonstrates a double displacement reaction where two aqueous solutions react to form an insoluble product. The key principle here is that when ions in solution combine to form an insoluble compound, a precipitate forms. The reaction &&\ce{Pb(NO3)2(aq) + 2KI(aq) -> PbI2(s) + 2KNO3(aq)}&& shows how lead iodide precipitates out as a bright yellow solid due to its low solubility in water, while potassium nitrate remains dissolved. This visual evidence confirms that a chemical reaction has occurred, as new substances with different properties are formed. Understanding precipitation reactions is crucial for applications in water treatment, qualitative analysis, and industrial chemistry. ,

💡 Fun Fact

Lead iodide (&&\ce{PbI2}&&) has been historically used as a bright yellow pigment in paints and dyes, though its use has declined due to toxicity concerns. The brilliant yellow colour you see in this experiment is the same colour that was once used to create “iodine yellow” in artistic paintings! Interestingly, lead iodide crystals have a beautiful hexagonal structure and can form stunning golden-yellow crystals when crystallized slowly. In modern times, lead iodide is being researched for use in radiation detectors and solar cells due to its unique electronic properties!

📌 Points to Remember

  • Double Displacement Reaction: A reaction where cations and anions of two compounds exchange places: &&\ce{AB + CD -> AD + CB}&&
  • Precipitation Reaction: A reaction that produces an insoluble solid (precipitate) from aqueous solutions
  • Lead Iodide: &&\ce{PbI2}&& is a bright yellow, insoluble compound formed in this activity
  • Balanced Equation: &&\ce{Pb(NO3)2(aq) + 2KI(aq) -> PbI2(s) + 2KNO3(aq)}&&
  • Solubility: The ability of a substance to dissolve in water determines whether a precipitate forms
  • Visual Evidence: Formation of a precipitate is clear evidence that a chemical reaction has occurred
  • Safety: Lead compounds are toxic – always handle with proper safety equipment and teacher supervision
  • State Symbols: (aq) = aqueous, (s) = solid, (l) = liquid, (g) = gas

Frequently Asked Questions (FAQ) ❓

Q1: What is Activity 1.2 in Class 10 Science Chapter 1?

Activity 1.2 is a practical experiment from the NCERT Class 10 Science textbook that demonstrates a double displacement reaction. In this activity, you mix lead nitrate solution (&&\ce{Pb(NO3)2}&&) with potassium iodide solution (&&\ce{KI}&&) in a test tube. The result is the immediate formation of a bright yellow precipitate of lead iodide (&&\ce{PbI2}&&), while potassium nitrate (&&\ce{KNO3}&&) remains dissolved in the solution. This activity provides visual evidence of a chemical reaction and helps students understand how ions exchange partners during reactions. ,

Q2: What is the yellow precipitate formed in Activity 1.2?

The yellow precipitate formed in Activity 1.2 is lead iodide (&&\ce{PbI2}&&). It appears as a bright yellow solid that settles at the bottom of the test tube. Lead iodide is insoluble in water at room temperature, which is why it precipitates out of the solution rather than remaining dissolved. The yellow colour is characteristic of lead iodide and makes this reaction easy to identify. The precipitate forms instantly when the two colourless solutions are mixed, providing dramatic visual evidence of the chemical reaction. ,

Q3: What type of reaction is demonstrated in Activity 1.2?

Activity 1.2 demonstrates a double displacement reaction (also called a double replacement or metathesis reaction). In this type of reaction, the cations and anions of two different compounds exchange places to form two new compounds. Specifically, lead ions (&&\ce{Pb^{2+}}&&) from lead nitrate combine with iodide ions (&&\ce{I^-}&&) from potassium iodide to form lead iodide, while potassium ions (&&\ce{K^+}&&) combine with nitrate ions (&&\ce{NO3^-}&&) to form potassium nitrate. This is also classified as a precipitation reaction because one of the products (lead iodide) is an insoluble solid that precipitates out of solution.

Q4: Why does a precipitate form in Activity 1.2?

A precipitate forms in Activity 1.2 because lead iodide (&&\ce{PbI2}&&) is insoluble in water. When lead nitrate and potassium iodide solutions are mixed, all four ions (&&\ce{Pb^{2+}}&&, &&\ce{NO3^-}&&, &&\ce{K^+}&&, and &&\ce{I^-}&&) are present in the solution. The lead ions and iodide ions have a strong attraction to each other and combine to form lead iodide. However, because lead iodide cannot dissolve in water, it immediately separates from the solution as a solid precipitate. Meanwhile, potassium nitrate is highly soluble and remains dissolved in the water. The formation of an insoluble product drives the reaction forward.

Q5: What safety precautions should be taken during Activity 1.2?

Safety is crucial when performing Activity 1.2 because lead compounds are toxic. Here are the essential precautions: (1) Always wear safety goggles and gloves to prevent contact with skin and eyes. (2) Perform the experiment only under teacher supervision. (3) Work in a well-ventilated area. (4) Never touch or taste the chemicals. (5) If any solution spills on your skin, wash immediately with plenty of water and inform your teacher. (6) Dispose of the waste properly according to your school’s laboratory guidelines – do not pour lead compounds down the drain. (7) Wash your hands thoroughly after the experiment. Lead is a heavy metal that can accumulate in the body and cause serious health problems, so proper handling is essential.

Q6: Can you give real-world applications of double displacement reactions?

Double displacement reactions have numerous practical applications in everyday life and industry: (1) Water Treatment: Precipitation reactions are used to remove harmful ions like lead, mercury, and arsenic from water by converting them into insoluble compounds that can be filtered out. (2) Photography: Silver halide precipitation reactions were historically used in photographic film development. (3) Medicine: Barium sulfate (&&\ce{BaSO4}&&), formed by a double displacement reaction, is used as a contrast agent in X-rays. (4) Qualitative Analysis: Chemists use precipitation reactions to identify unknown ions in solutions. (5) Manufacturing: Production of pigments, dyes, and other chemicals often involves precipitation reactions. (6) Soap Making: The reaction between fats and sodium hydroxide involves double displacement. These applications show how understanding simple lab reactions helps us solve real-world problems!

Q7: How do you write the balanced equation for Activity 1.2?

To write the balanced equation for Activity 1.2, follow these steps: Step 1: Write the formulas of reactants and products: &&\ce{Pb(NO3)2 + KI -> PbI2 + KNO3}&&. Step 2: Count atoms on each side. Lead nitrate has 2 nitrate groups, so we need 2 potassium nitrate molecules on the product side. Step 3: To get 2 potassium atoms, we need 2 molecules of potassium iodide on the reactant side. Step 4: Check: This also gives us 2 iodide atoms, which is correct for lead iodide (&&\ce{PbI2}&&). Final balanced equation: &&\ce{Pb(NO3)2(aq) + 2KI(aq) -> PbI2(s) + 2KNO3(aq)}&&. The coefficient 2 before KI and KNO3 ensures that we have the same number of each type of atom on both sides, following the Law of Conservation of Mass. Don’t forget to include state symbols: (aq) for aqueous and (s) for solid!

Q8: What is the difference between a precipitate and a sediment?

Though they may look similar, precipitates and sediments are formed by different processes: A precipitate is a solid that forms as a result of a chemical reaction in a solution. For example, the yellow lead iodide in Activity 1.2 is a precipitate because it forms when two dissolved compounds react chemically. The formation of a precipitate involves breaking old chemical bonds and forming new ones, creating a new substance with different properties. On the other hand, a sediment is solid particles that settle out of a suspension due to gravity, without any chemical reaction occurring. For example, if you mix sand with water and let it stand, the sand will settle at the bottom as sediment – but it’s still sand, not a new substance. The key difference is: precipitates result from chemical changes, while sediments result from physical settling.

📚 Further Reading

For more NCERT Solutions for Class 10 Science, visit the official NCERT website. You can also explore our complete Chapter 1: Chemical Reactions and Equations solutions for detailed explanations of all questions and activities. To deepen your understanding, check out Activity 1.1 on combustion reactions and other related topics.


📖 Sources and References

: Physics Catalyst – Activity 1.2 Class 10 Science: Exploring Chemical Reactions. Available at: https://physicscatalyst.com/article/activity-1-2-class-10-science/

: Bank of Biology – Chemical Reactions and Equations | Activity 1.2 with Solution. Available at: https://www.bankofbiology.com/2021/03/chemical-reactions-and-equations_11.html

: Remedial Classes – Activity 1.2 Class 10 Science. Available at: https://www.remedialeducationpoint.com/2024/11/activity-class-10th-science.html

: Scribd – Chemical Reactions and Equations (Activity) PDF. Available at: https://www.scribd.com/document/746499309/Chemical-Reactions-and-Equations-Activity

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